Investigation of Mechanical and Thermal Properties of Novel Hybrid Composites Based on Areca Nut Shell and Pineapple Leaf Powder Reinforced Vinyl Ester Matrix
DOI:
https://doi.org/10.21467/preprints.704Abstract
Renewability, cheap cost, and sustainability have recently made eco-friendly materials popular. As a result, both academic and industrial fields are paying great attention to seeking bio-based filler materials for the creation of composites. The study is intended to investigate the utilisation of solid biomass waste in the hybrid form of Areca Nut Shell Powder (ASP) and Pineapple Leaf Powder (PLP) as fillers in vinyl ester-based composites. This process has been investigated for the first time using the hand lay-up technique. These filler substances are agricultural by-products that can be obtained from renewable sources at a low cost. Their mechanical and thermal properties were assessed for hybrid fillers included in the matrix at filler contents from 0 to 20 wt.%. Usually, adding hybrid fillers improved mechanical properties but had a small effect on thermal ones. The hybrid filler-reinforced composites showed notable increases in flexural, impact, and Shore D hardness characteristics in comparison to the neat vinyl ester resin, with improvements of 1.53 times, 1.66 times, and 1.35 times, respectively, at 16 wt.% filler loading, while the tensile strength displayed a steady decline. Using TGA and HDT techniques, thermal stability was evaluated, revealing an HDT value as high as 112°C. Given the results, these hybrid filler-reinforced composites could be appropriate for use in sectors including transportation and building, where moderately tough and thermally stable composites are required and where cost is a major concern.
Keywords:
Agricultural waste composites, Areca Nut Shell Powder, Pineapple Leaf PowderDownloads
References
Sathish Kumar RK, Sasikumar R, Dhilipkumar T. Exploiting agro-waste for cleaner production: A review focusing on biofuel generation, bio-composite production, and environmental considerations. J Clean Prod 2024;435. https://doi.org/10.1016/j.jclepro.2023.140536.
Bharath KN, Basavarajappa S. Applications of biocomposite materials based on natural fibers from renewable resources: A review. Science and Engineering of Composite Materials 2016;23:123–33. https://doi.org/10.1515/secm-2014-0088.
Volpe V, Pantani R. Natural fiber-reinforced light composites for the automotive industry. Polym Compos 2025. https://doi.org/10.1002/pc.29518.
Mita?ová Z, Litecká J, Duplák J. Agro-Fiber Based Composites With Use in Automotive Industry. TEM Journal 2024:2429–35. https://doi.org/10.18421/TEM133-70.
McNeill DC, Pal AK, Nath D, Rodriguez-Uribe A, Mohanty AK, Pilla S, et al. Upcycling of ligno-cellulosic nutshells waste biomass in biodegradable plastic-based biocomposites uses - a comprehensive review. Composites Part C: Open Access 2024;14. https://doi.org/10.1016/j.jcomc.2024.100478.
World Food and Agriculture – Statistical Yearbook 2024. 2024. https://doi.org/10.4060/cd2971en.
Katipalla A, Ballal P, Shivanna NK. Areca Nut Husk: A Burning Issue? Indian Journal of Respiratory Care 2024;13:140–1. https://doi.org/10.5005/jp-journals-11010-1108.
Lalhmunsiama, Lee SM, Choi SS, Tiwari D. Simultaneous removal of Hg(II) and phenol using functionalised activated carbon derived from Areca nut waste. Metals (Basel) 2017;7. https://doi.org/10.3390/met7070248.
Sharma SR, S SS. Use of areca-nut husk ash (AHA) in brick preparation and its impact analysis 2022. https://doi.org/10.21203/rs.3.rs-1578847/v1.
Mishra RK, Gariya B, Savvasere P, Dhir D, Kumar P, Mohanty K. Thermocatalytic Pyrolysis of Waste Areca Nut into Renewable Fuel and Value-Added Chemicals. ACS Omega 2024;9:25779–92. https://doi.org/10.1021/acsomega.3c10184.
Fouda-Mbanga BG, Tywabi-Ngeva Z. Application of Pineapple Waste to the Removal of Toxic Contaminants: A Review. Toxics 2022;10. https://doi.org/10.3390/toxics10100561.
Sangma ARW, Joshi SR. Areca nut: Traditional processing, uses and products potential of the husk. n.d.
Azhar Ekoputra F, Ismail I. Effect a Chemical Treatment of Pineapple Leaf Fiber (PALF) for Mechanical Properties as a Reinforced Composite Matrix Polyesters. n.d.
Nagaprasad N, Vignesh V, Karthik Babu NB, Manimaran P, Stalin B, Ramaswamy K. Effect of green hybrid fillers loading on mechanical and thermal properties of vinyl ester composites. Polym Compos 2022;43:7928–39. https://doi.org/10.1002/pc.26925.
Babu NBK, V V, Arun Balasubramanian K, S KD, Khan A, Hashem M, et al. Effect of natural hybrid fillers reinforced vinyl ester composites on mechanical and physical properties. Mater Res Express 2024;11:105504. https://doi.org/10.1088/2053-1591/ad8105.
Jagadeesh P, Puttegowda M, Thyavihalli Girijappa YG, Rangappa SM, Siengchin S. Effect of natural filler materials on fiber reinforced hybrid polymer composites: An Overview. Journal of Natural Fibers 2022;19:4132–47. https://doi.org/10.1080/15440478.2020.1854145.
Zhao Y, Kikugawa G, Kawagoe Y, Shirasu K, Okabe T. Molecular-scale investigation on relationship between thermal conductivity and the structure of crosslinked epoxy resin. Int J Heat Mass Transf 2022;198. https://doi.org/10.1016/j.ijheatmasstransfer.2022.123429.
Di Landro L, Janszen G. Composites with hemp reinforcement and bio-based epoxy matrix. Compos B Eng 2014;67:220–6. https://doi.org/10.1016/j.compositesb.2014.07.021.
Bahrami M, Abenojar J, Martínez MÁ. Recent progress in hybrid biocomposites: Mechanical properties, water absorption, and flame retardancy. Materials 2020;13:1–46. https://doi.org/10.3390/ma13225145.
Sathish Kumar RK, Sasikumar R, Nagaprasad N, Ezhilvannan R, Krishnaraj R. Investigation of Mechanical and Thermal Stabilities of Tamarind Seed- and Peanut Shell Powder-Reinforced Vinyl Ester Composite. Advances in Materials Science and Engineering 2024;2024. https://doi.org/10.1155/2024/8818030.
Stalin A, Mothilal S, Vignesh V, Sanjay MR, Siengchin S. Mechanical properties of hybrid vetiver/banana fiber mat reinforced vinyl ester composites. Journal of Industrial Textiles 2022;51:5869S-5886S. https://doi.org/10.1177/1528083720938161.
Ramakrishnan M, Ramasubramanian S, Raman SS, Chinnapalanichamy J. Evaluation of the physical, mechanical, water absorption, and tribological behavior of pineapple leaf fiber/roselle fiber reinforced vinyl ester hybrid composites for non-structural applications. Polym Compos 2023;44:5284–95. https://doi.org/10.1002/pc.27491.
Stalin B, Nagaprasad N, Vignesh V, Ravichandran M. Evaluation of mechanical and thermal properties of tamarind seed filler reinforced vinyl ester composites. Journal of Vinyl and Additive Technology 2019;25:E114–28. https://doi.org/10.1002/vnl.21701.
Thangaraj S, Pradeep GM, Heaven Dani MS, Mayakannan S, Benham A. Experimental investigations on tensile and compressive properties of nano alumina and arecanut shell powder reinforced polypropylene hybrid composites. Mater Today Proc, vol. 68, Elsevier Ltd; 2022, p. 2243–8. https://doi.org/10.1016/j.matpr.2022.08.442.
Eze IO, Igwe IO, Ogbobe O, Anyanwu EE, Nwachukwu I. Mechanical Properties of Pineapple Leaf Powder Filled High Density Polyethylene. International Journal of Engineering and Technologies 2016;9:13–9. https://doi.org/10.18052/www.scipress.com/ijet.9.13.
Palanisamy S, Palanisami K, Madeshwaren V. Nano iron particles influence on mechanical properties and morphological analysis of polymer composites. Revista Materia 2025;30. https://doi.org/10.1590/1517-7076-RMAT-2024-0698.
Io E, Io I, Ogbobe O, Hc O, Ul E, Sc N, et al. Effects of Hydrogen Peroxide Treated Pineapple Leaf Powder on Mechanical Properties of High Density Polyethylene Composites. vol. 4. 2017.
Selamat MZ, Zhafri Tahir MS, Kasim AN, Dharmalingam S, Putra A, Yaakob MY, et al. Effect of starch sizes particle as binder on short pineapple leaf fiber composite mechanical properties. MATEC Web of Conferences 2018;150:04008. https://doi.org/10.1051/matecconf/201815004008.
Somashekhara J, Ramesh B T, Vinay Belagavi, Madhu H T. Investigation and Study of Mechanical Properties of Areca Shell Fiber and Palm Powder Natural Composites. IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE) 2018;15:62–73.
Hu C, Battampara P, Guna V, Reddy N. Effect of Alkali Treatment on the Structure and Properties of Natural Cellulose Fibers from Areca Cathechu Shells. Journal of Natural Fibers 2022;19:9754–64. https://doi.org/10.1080/15440478.2021.1993405.
Cheirmakani BM, Subburaj B, Balasubramanian V. Exploring the Properties of Pineapple Leaf Fiber and Prosopis Julifora Powder Reinforced Epoxy Composite. Journal of Natural Fibers 2022;19:2065–76. https://doi.org/10.1080/15440478.2020.1798844.
Dev S, Shah PN, Zhang Y, Ryan D, Hansen CJ, Lee Y. Synthesis and mechanical properties of flame retardant vinyl ester resin for structural composites. Polymer (Guildf) 2017;133:20–9. https://doi.org/10.1016/j.polymer.2017.11.017.
Jaswal S, Gaur B. New trends in vinyl ester resins. Reviews in Chemical Engineering 2014;30:567–81. https://doi.org/10.1515/revce-2014-0012.
Melnychuk M, Shevchuk I, Kashytskyi V, Feshcuk Y, Polivoda N. Mechanical Properties of Hybrid Composites Based on Polypropylene Modified with Natural Fillers, 2023, p. 221–9. https://doi.org/10.1007/978-3-031-32774-2_22.
Kandelbauer A, Tondi G, Zaske OC, Goodman SH. Unsaturated polyesters and vinyl esters. Handbook of Thermoset Plastics, Elsevier; 2022, p. 97–158. https://doi.org/10.1016/B978-0-12-821632-3.00015-4.
Downloads
Posted
Section
Categories
License
Copyright (c) 2025 R K Sathish Kumar

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Any non-commercial use, distribution, adaptation, and reproduction in any medium is permitted as long as the original work is properly cited. However, caution and responsibility are required when reusing as the articles on the preprint server are not peer-reviewed. Readers are advised to check for the availability of any updated or peer-reviewed version.